Does anyone know the relative merits of each technique? Is one more durable, or is it purely esthetics?
Thanks
hi Pheroze,
Color case hardening is accomplished in one of two ways.. The traditional method, and the most durable is to heat the metal in a container with both hardwood charcoal and bone charcoal. It is heated to somewhere around 1,200 to 1,400 degrees and then quenched. The other method to accomplish a brighter set of colors but a less durable finish is to use cyanide to treat the metal. The first one you can do at home, the second, not so much. Neither are as tough as bluing in terms of durability. Also a side note, if you ever see
shiny color case hardening, it has been clear coated and the coating will eventually flake. untreated color case is a flat finish. There is no way to bring a metal to those temps and keep it shiny. Turnbull restorations can do any of these for you.
Bluing is a controlled rusting of the surface into magnetite or black oxide. This produces a very durable finish as black iron oxide is actually harder than the steel beneath it. There are a couple ways to accomplish this.
One is called rust bluing and is what I did
here. It is a process of repeatedly treating the metal with a specific acid solution, letting it rust evenly, then boiling or steaming it to turn the red rust into black oxide (tacking an extra oxygen on it). Then it is carded off with either steel wool or a carding brush and the process is repeated until the finish is the desired color (usually 6-8 times but up to 20 depending on the steel). This produces a soft luster to the steel and is the most authentic finish for a traditional rifle's metal. It is also quite durable.
Hot or Caustic Bluing involves immersing the metal in a tank of lye and nitrate salts that has been brought up to between 275 and 295 degrees. The temperature is critical as too hot or too cold will ruin the finish. This produces a deep black which is very durable. This is the finish on almost all factory made rifles that do not contain soft solder. Soft solder will dissolve/melt in the bath so anything with solder on it, (double rifles/ shotguns, soldered on sights, etc,) cannot be caustic blued. They must be rust blued.
The last common type of bluing is used only on small parts and is not terribly durable but produces a beautiful bluish purple that accents the guns blackened finish. It is known as Nitre Bluing and is accomplished by simply bringing steel up to a its second stage temp of oxidation (700 degrees) in the presence of oxygen. The easiest way to do this evenly is to immerse it in a bath of liquid nitrate salts that is held at that temp until it turns blue, then it is quenched. You can also accomplish this with a torch but you have to be incredibly careful as you can overheat one section very quickly. It is a popular thing to do to screws and other small parts to accent the gun.
Hope this was somewhat informative!